ASTM D4084-23 PDF

SIGNIFICANCE AND USE 5.1 This test method is useful in determining the concentration of hydrogen sulfide in gaseous samples and in verifying compliance with operational needs and/or environmental limitations for H2S content. The automated performance operation of this method allows unattended measurement of H2S concentration. The user is referred to Practice D7166 for unattended on-line use of instrumentation based upon the lead acetate reaction rate method. SCOPE 1.1 This test method covers the determination of hydrogen sulfide (H2S) in gaseous fuels. It is applicable to the measurement of H2S in natural gas, liquefied petroleum gas (LPG), substitute natural gas, landfill gas, sewage treatment off gasses, recycle gas, flare gasses, and mixtures of fuel gases. This method can also be used to measure the hydrogen sulfide concentration in carbon dioxide. Air does not interfere. The applicable range is 0.1 to 16 parts per million by volume (ppm/v) (approximately 0.1 to 22 mg/m3) and may be extended to 100 % H2S by manual or automatic volumetric dilution. 1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.