ASTM D8560-24 PDF
Standard Guide for Determination of Airborne PFAS in the Indoor Air Environment
Standard Guide for Determination of Airborne PFAS in the Indoor Air Environment
- Статус документа:
- Действующий
- Формат:
- Электронный (PDF)
- Количество страниц:
- 21
- Дата публикации:
- 1 апреля 2024 г.
- Издание:
- D8560
- Технический комитет:
- D22 - Air Quality
SIGNIFICANCE AND USE 5.1 Some PFAS have been implicated in adverse human health impacts (4, 5, 6). Therefore, quantifying PFAS concentrations in indoor air is important for accurate and meaningful exposure analysis and risk assessments. 5.2 PFAS found in air can have a wide range of chemical characteristics that will impact sampling practice selection. For example, estimated vapor pressure values can vary by ten orders of magnitude, while estimated Henry’s Law constants can vary by five orders of magnitude (Table 1). This means that sampling and analytical methods that are appropriate for one PFAS compound may not be appropriate for other PFAS compounds. Hence, prior to sampling and selecting analytic methods for PFAS measurement in indoor air, it is critical to establish that the chosen PFAS sampling method(s) is appropriate for the target compound(s), the sampling location, and the environmental conditions. 5.3 The measurement of PFAS in indoor air is an active and growing research topic. Understanding of PFAS properties, sampling and analytic approaches and techniques is constantly evolving. This includes the determination of physical-chemical properties of many PFAS, which may not even have been measured experimentally or which have a wide range of experimentally determined properties (that is, 8:2 FTOH in Table 1). This guide describes methods that are in use at the time of publication. 5.4 PFAS in indoor air may come from a wide range of sources, including consumer products, building materials, food packaging, outdoor air, and other miscellaneous sources. PFAS is also commonly quantified in indoor dust. There are several methods that quantify these chemicals in solid and liquid media including, but not limited to Guide E3302, Test Method D7968, Test Method D7979, Test Method D8421, Test Method D8535, US EPA 533, and US EPA 537.1. US EPA OTM-45 quantifies some PFAS in the combined gas and particle phases of stationary sources, such as incinerator stack sampling. 5.5 Thi... SCOPE 1.1 This guide describes methods for determining Per- and Polyfluoroalkyl Substances (PFAS) concentrations in indoor air. 1.2 This guide is focused on PFAS measurement technologies applicable to indoor air (including in vehicles and indoor workplaces) and other relevant air volumes such as, air in chambers, bags, or both. The described technologies were developed for indoor air; they may or may not be applicable to other types of air samples. 1.3 This guide describes available technologies and methods that can be used to measure indoor air PFAS concentrations in the gaseous or particulate phases, or both, in indoor air. 1.4 This guide describes each method and its advantages and limitations. 1.5 This guide does not attempt to differentiate between the effectiveness of the methods nor determine equivalence of the methods. 1.6 The sorbent-based sampling strategies addressed in this guide are for PFAS compounds with a molecular mass greater than 200 g mol-1 (1, 2, 3).2 Compounds less than 200 g mol-1, such as CF4, C2F6, or PFAS degradation products may require real-time analytical methods described in this guide or other methods that are not presented here. 1.7 Units—The values stated in SI units are to be regarded as the standard. No other units of measurement are included in this standard. 1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Abstract
Overview
ASTM D8560-24, Standard Guide for Determination of Airborne PFAS in the Indoor Air Environment, establishes techniques for measuring per- and polyfluoroalkyl substances (PFAS) concentrations in indoor air. Recognizing the potential adverse health effects linked to some PFAS compounds, this guide provides best practices for sampling and analytical methods. It encompasses environments such as buildings, vehicles, and workplace settings, helping organizations and researchers perform accurate exposure assessments and risk analyses related to airborne PFAS.
This standard is developed by ASTM to align with internationally recognized principles, ensuring consistency and reliability in the determination of indoor air PFAS worldwide.
Key Topics
- PFAS Measurement Technologies: The standard outlines current technologies suitable for indoor air sampling, covering gas and particulate phases.
- Phase-Appropriate Methods: Not all PFAS share the same chemical properties; therefore, the guide emphasizes that sampling and analysis methods must be chosen based on the specific PFAS compounds, environmental conditions, and sampling objectives.
- Sampling Strategies: Describes both active and passive strategies, including sorbent-based approaches for compounds with molecular mass greater than 200 g/mol.
- Practical Limitations & Considerations: Offers guidance on advantages and limitations of various methods, stressing the importance of method suitability and quality control.
- Emerging Research: Recognizes rapid advancements in PFAS research and encourages regular review of methods as new information and technologies become available.
- Sources of Indoor PFAS: Identifies the variety of indoor PFAS sources, such as consumer products, building materials, food packaging, and infiltration from outdoor air, along with their typical inclusion in indoor dust.
Applications
- Exposure and Risk Assessment: Enables environmental health and safety professionals, building owners, and regulatory agencies to quantify PFAS concentrations in indoor air, which is vital for assessing potential human exposure and conducting health risk analyses.
- Indoor Air Quality Management: Supports the development of monitoring and mitigation strategies in indoor environments, especially in locations with known PFAS emissions or use of PFAS-containing materials.
- Research and Policy: Provides standardized methods for academic and industrial researchers investigating PFAS dynamics, sources, or mitigation. The guide also helps policymakers establish regulatory or voluntary indoor air quality guidelines involving PFAS.
- Workplace Safety: Assists organizations in evaluating workplace exposures in environments such as manufacturing plants, laboratories, or any site where PFAS may be present or processed.
Related Standards
ASTM D8560-24 references and complements several international methods and standards for PFAS and indoor air analysis, including:
- ASTM E3302: Guide for PFAS Analytical Methods Selection
- ASTM D7968, D7979, D8421, D8535: Test methods for PFAS in soil, water, and biosolid matrices
- ASTM D8141: Guide for VOC and SVOC Emission Testing Methods
- ISO 16000-6, ISO 16017-1: International standards for indoor air sampling and analysis
- US EPA Methods 533, 537.1, and OTM-45: US EPA methods for PFAS determination in drinking water and stationary source air emissions
Practical Value
Implementing ASTM D8560-24 in indoor environments provides:
- Enhanced Accuracy: Consistent, scientifically robust approaches for PFAS detection increase the reliability of exposure data.
- Comprehensive Guidance: Clear instructions for method selection, practical implementation, and awareness of limitations help users navigate the complexities of PFAS sampling.
- Current Relevance: Adopts methods recognized by both ASTM and major international and regulatory bodies, ensuring broad acceptability and harmonization in global reporting.
- Supports Compliance: Facilitates adherence to regulatory and institutional requirements concerning indoor air quality and occupational health with regards to PFAS.
By integrating ASTM D8560-24, stakeholders can better protect human health, meet environmental responsibilities, and contribute to a growing body of knowledge on PFAS in the indoor environment.
Технические детали
- SKU
- ASTM D8560-24
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