ASTM D890-12(2022) PDF
Standard Test Method for Water in Liquid Pine Chemicals
Standard Test Method for Water in Liquid Pine Chemicals
- Статус документа:
- Действующий
- Формат:
- Электронный (PDF)
- Количество страниц:
- 3
- Дата публикации:
- 1 декабря 2022 г.
- Издание:
- D890
- ICS:
- 87.060.30
SIGNIFICANCE AND USE 3.1 Many pine chemical products contain water as a result of the processes used for their production. Typically refined products such as terpenes, pine oil, tall oil fatty acids, and distilled tall oil contain only traces of water, but crude tall oil might contain 0.5 % to 2.5 % of water. Although the Karl Fischer and coulometric methods are most applicable to low levels of moisture, these can be and are used at higher levels. The azeotropic distillation method is generally used at higher levels. SCOPE 1.1 These test methods cover the quantitative determination of dissolved or occluded water present in any proportion in liquid pine chemicals, such as turpentine, pinene, dipentene, pine oil, tall oil, and tall oil fatty acids. Three methods of moisture testing are included. The Karl Fisher titration method is the preferred method for testing tall oil, Test Methods D803. 1.1.1 The Karl Fischer Titration method is based on the reaction between water and a complex reagent2 consisting of iodine, sulfur dioxide, pyridine, and methanol, whereby the iodine is converted to a colorless compound. The appearance of a persistent iodine color in the reaction mixture indicates the complete removal of free water by reaction with the reagent, and the endpoint may be measured colorimetrically. Automatic titrators find this endpoint by the restoration of a current strength when the resistance provided by the presence of water is eliminated. Amperometric automatic titrators find this endpoint by detecting the current flow that occurs once water is eliminated. 1.1.2 The coulometric titration method determines water content by electronic integration of a current sufficient to generate the precise amount of iodine from the required reagent to react with the water in the sample. 1.1.3 The azeotropic method utilizes the relatively low boiling point of water, as compared with other sample constituents, in a toluene or xylene matrix so that water is collected in a trap and measured. 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Abstract
Overview
ASTM D890-12(2022) - Standard Test Method for Water in Liquid Pine Chemicals - defines quantitative methods for determining water content in various liquid pine chemicals. These products include turpentine, pinene, dipentene, pine oil, tall oil, and tall oil fatty acids, which may contain dissolved or occluded water from production processes. The standard provides three recognized test methods for water quantification, ensuring product quality consistency and process reliability across industries involved with pine-derived chemicals.
Key Topics
-
Test Methods Included:
- Karl Fischer Titration (preferred for tall oil): Utilizes a chemical reaction involving iodine to precisely measure low levels of water content.
- Coulometric Titration: Employs electronic integration for generating required iodine and reacting with water in the sample.
- Azeotropic Distillation: Uses differences in boiling points to collect and measure water, suitable for higher moisture levels.
-
Applicable Products:
- Turpentine
- Pinene
- Dipentene
- Pine oil
- Tall oil (crude and refined)
- Tall oil fatty acids
-
Result Reporting:
- Results expressed in SI units and reported to the nearest 0.01% or 0.1%, depending on the method used.
-
Principles of Standardization:
- Developed according to internationally recognized principles, supporting global trade and regulatory compliance.
Applications
-
Quality Control in Pine Chemicals Accurate moisture determination is crucial for manufacturers and quality control laboratories to ensure product consistency in pine oil, turpentine, and related derivatives.
-
Optimizing Industrial Processes Understanding water content helps optimize further processing steps and prevents issues such as unwanted reactions, product instability, or yield loss.
-
Regulatory and Trade Compliance Compliance with ASTM D890-12(2022) supports international regulatory requirements and smooth facilitation of pine chemical trade, aligning with the World Trade Organization (WTO) Technical Barriers to Trade (TBT) principles.
-
Laboratory Operations Laboratories performing analyses on pine chemicals require standardized, reliable methods for water detection, both for internal process control and contract testing services.
Related Standards
- ASTM D803 - Test Methods for Testing Tall Oil
- ASTM D1364 - Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method)
Following ASTM D890-12(2022) ensures laboratory and industrial laboratories use internationally accepted methods for quantifying water in liquid pine chemicals. Adhering to these standardized test methods safeguards product quality, enhances laboratory credibility, and ensures compliance with both domestic and international regulations.
Keywords: water in pine chemicals, ASTM D890, Karl Fischer titration, pine oil moisture, azeotropic distillation, coulometric titration, tall oil, turpentine, pine chemical testing, international standards compliance
Технические детали
- Технический комитет
- D01 - Paint and Related Coatings, Materials, and Applications
- SKU
- ASTM D890-12(2022)
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