ASTM E3282-22 PDF
Standard Guide for NAPL Mobility and Migration in Sediments – Evaluation Metrics
Standard Guide for NAPL Mobility and Migration in Sediments – Evaluation Metrics
- Статус документа:
- Действующий
- Формат:
- Электронный (PDF)
- Количество страниц:
- 41
- Дата публикации:
- 1 июня 2022 г.
- Издание:
- E3282
- ICS:
- 13.080.01
SIGNIFICANCE AND USE 4.1 Hydrophobic organic liquids (for example, petroleum hydrocarbons, coal tars) may exist in the environment for long periods of time as NAPLs. Standardized guidance and test methods do not exist to assess NAPL movement (both pore-scale mobility and NAPL body-scale migration) in sediment. Literature searches have resulted in a limited body of available and applicable research. Current research has focused on site-specific sediment NAPL movement evaluation approaches. 4.2 Standardized guidance and test methods currently exist for assessing NAPL mobility and migration at upland sites, from organizations such as ASTM International (Guides E2531 and E2856), Interstate Technology and Regulatory Council (2), and the American Petroleum Institute (3, 4). Approaches commonly used in upland sites may or may not be applicable for any given sediment site. This guide provides perspectives on the applicability of various methodologies for specific sediment conditions. 4.3 This guide describes various methodologies that are useful in sediment NAPL movement evaluation, such as laboratory test methods, calculation approaches, and field observation interpretation. The guide then provides frameworks to evaluate the data generated from these methodologies to determine if the NAPL observed in the sediments under in situ conditions exhibits movement of any kind. 4.4 Important exposure pathways in upland sites are usually not applicable to sediment sites. The U.S. Environmental Protection Agency notes, “Contaminants in the biologically active layer of the surface sediment at a site often drive exposure” (5). In aquatic environments, benthic organisms live in the surface sediment to maintain access to oxygenated overlying water. These benthic organisms are at the base of the food chain. If NAPL in subsurface sediment is not migrating, the NAPL will not move into the surface sediment and result in exposure to benthic organisms. NAPL that is stable and only present in subsurface se... SCOPE 1.1 This guide discusses methodologies that can be applied to evaluate the potential for the movement (that is, pore-scale mobility or NAPL body-scale migration) of non-aqueous phase liquid (NAPL) in sediments. NAPL movement assessment in sediments is significantly different than in upland soils. As such, the frameworks for evaluating NAPL movement in upland soils have limited applicability for sediments. In particular, because upland NAPL conceptual site models may not be applicable to many sediment sites, this guide provides a framework to evaluate whether NAPL is mobile (at the pore scale) or migrating (at the NAPL body scale) in sediments. 1.2 Assessment of the potential for NAPL to move in sediment is important for several reasons, including (but not limited to) evaluation of risk to potential receptors, the need for potential remedial action, and potential remedial strategies. For example, if the NAPL is migrating, sensitive receptors may be impacted and this will influence the choice and timing of any remedy selected for an area of the sediment site. If the NAPL is not mobile or migrating, then remedial actions may not be warranted. 1.3 This guide is applicable at sediment sites where NAPL has been identified in the sediment by various screening methods and the need for a NAPL movement evaluation is warranted (Guide E3248). 1.4 Petroleum hydrocarbon, coal tar, and other tar NAPLs (including fuels, oils, and creosote) are the primary focus of this guide. These forms of contamination are commonly related to historical operations at refineries, petroleum distribution terminals, manufactured gas plants (MGPs), and various large industrial sites. 1.5 Although certain technical aspects of this guide apply to other NAPLs (for example, dense NAPLs [DNAPLs] such as chlorinated hydrocarbon solvents), this guide does not completely address the additional complexities of those DNAPLs. 1.6 The goal of this guide...
Abstract
Overview
ASTM E3282-22: Standard Guide for NAPL Mobility and Migration in Sediments – Evaluation Metrics provides comprehensive guidance for evaluating the movement potential of non-aqueous phase liquids (NAPLs) in sediments. Hydrophobic contaminants such as petroleum hydrocarbons and coal tars may persist in sediment environments for extended periods, posing unique assessment challenges compared to upland sites. This standard addresses the absence of uniform methodologies for assessing NAPL mobility and migration at sediment sites by outlining frameworks, key concepts, laboratory and field approaches, and evaluation metrics.
Key Topics
- NAPL Mobility and Migration: The standard distinguishes between pore-scale mobility (movement of NAPL within interconnected sediment pores) and NAPL body-scale migration (overall movement of a NAPL body through sediment). It provides evaluation frameworks for both.
- Sediment-Specific Methodologies: Existing upland site assessment tools cannot be directly applied to sediment sites. ASTM E3282-22 describes tailored laboratory test methods, calculation approaches, and field observations for sediment environments.
- Screening and Evaluation: Various screening methods, including core sample analysis, visual observations, UV light, and laser-induced fluorescence, are discussed to identify NAPL presence, distribution, and movement potential.
- Tiered and Weight of Evidence Frameworks: The guide encourages using tiered or weight of evidence (WOE) approaches, integrating multiple lines of evidence to assess whether NAPL is mobile or migrating.
- Exposure and Risk Relevance: The evaluation of NAPL movement directly affects risk assessment for benthic (bottom-dwelling) organisms and human health since exposure is often linked to NAPL migration into biologically active surface sediments.
Applications
ASTM E3282-22 is vital for:
- Site Characterization: Determining whether NAPL in sediment is mobile or stable is a prerequisite for developing accurate conceptual site models (CSMs). This informs risk management, remedial action selection, and long-term monitoring strategies.
- Risk Assessment: By evaluating NAPL movement, stakeholders can assess the risk to sensitive receptors-such as aquatic life in surface sediments-and to overall ecological and human health.
- Remediation Decision-Making: The standard supports informed decisions on remediation necessity and approach. For example:
- If NAPL is immobile and remains in subsurface sediments, remediation may not be necessary.
- If NAPL is migrating, more proactive or urgent response actions may be required.
- Regulatory Compliance and Stakeholder Communication: This guide can complement and support regulatory frameworks and enhance communication among environmental consultants, regulators, site owners, and community members.
Related Standards
Key referenced and related ASTM standards include:
- ASTM E2531: Guide for Development of Conceptual Site Models and Remediation Strategies for Light Nonaqueous-Phase Liquids Released to the Subsurface
- ASTM E2856: Guide for Estimation of LNAPL Transmissivity
- ASTM E3248: Guide for NAPL Mobility and Migration in Sediment – Conceptual Models for Emplacement and Advection
- ASTM E3281: Guide for NAPL Mobility and Migration in Sediments – Screening Process to Categorize Samples for Laboratory NAPL Mobility Testing
- ASTM E3300: Guide for NAPL Mobility and Migration in Sediment – Evaluating Ebullition and Associated NAPL/Contaminant Transport
Practical Value
Implementing ASTM E3282-22 helps environmental professionals:
- Support science-based decision-making related to sediment contamination.
- Apply consistent, defensible methods for NAPL movement evaluation in sediment management programs.
- Address site complexities with flexible, adaptive frameworks that evolve as new data and research emerge.
- Optimize remediation investments and protect ecological and human health by differentiating between stable and migrating NAPL zones.
Keywords: ASTM E3282-22, NAPL mobility, NAPL migration, sediment contamination, petroleum hydrocarbons, site characterization, risk assessment, environmental remediation, sediment sites, NAPL sediment evaluation.
Технические детали
- Технический комитет
- E50 - Environmental Assessment, Risk Management and Corrective Action
- SKU
- ASTM E3282-22
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