ISO 16017-1:2000
Indoor, ambient and workplace air — Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography — Part 1: Pumped sampling
Indoor, ambient and workplace air — Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography — Part 1: Pumped sampling
- Статус документа:
- Действующий
- Формат:
- Электронный (PDF)
- Количество страниц:
- 32
- Дата публикации:
- 23 ноября 2000 г.
- Издание:
- ISO IS 16017 edition 1 version 1
- ICS:
- 13.040.01
This part of ISO 16017 gives general guidance for the sampling and analysis of volatile organic compounds (VOCs) in air. It is applicable to ambient, indoor and workplace atmospheres and the assessment of emissions from materials in small- or full-scale test chambers. This part of ISO 16017 is appropriate for a wide range of VOCs, including hydrocarbons, halogenated hydrocarbons, esters, glycol ethers, ketones and alcohols. A number of sorbents 1) are recommended for the sampling of these VOCs, each sorbent having a different range of applicability. Very polar compounds will generally require derivatization, very low boiling compounds will only be partially retained by the sorbents, depending on ambient temperature, and can only be estimated qualitatively. Semi-volatile compounds will be fully retained by the sorbents, but may only be partially recovered. Compounds for which this part of ISO 16017 has been tested are given in tables. This part of ISO 16017 may be applicable to compounds not listed, but in these cases it is advisable to use a back-up tube containing the same or a stronger sorbent. This part of ISO 16017 is applicable to the measurement of airborne vapours of VOCs in a concentration range of approximately 0,5 _g/ m3 to 100 mg/m3 individual compound. The upper limit of the useful range is set by the sorptive capacity of the sorbent used and by the linear dynamic range of the gas chromatograph column and detector or by the sample-splitting capability of the analytical instrumentation used. The sorptive capacity is measured as a breakthrough volume of air, which determines the maximum air volume that shall not be exceeded when sampling. The lower limit of the useful range depends on the noise level of the detector and on blank levels of analyte and/or interfering artefacts on the sorbent tubes. Artefacts are typically sub-nanogram for well-conditioned Tenax GR and carbonaceous sorbents such as Carbopack/Carbotrap type materials, carbonized molecular sieves and molecular sieves such as Spherocarb, or pure charcoal; at low nanogram levels for Tenax TA and at 5 ng to 50 ng levels for other porous polymers such as Chromosorbs and Porapaks. Sensitivity is typically limited to 0,5 _g/m_ for 10-litre air samples with this latter group of sorbents because of their inherent high background. The procedure specified in this part of ISO 16017 is applicable to low flowrate personal sampling pumps and gives a time-weighted average result. It is not applicable to the measurement of instantaneous or short-term fluctuations in concentration. 1) The sorbents listed in annex C and elsewhere in this International Standard are those known to perform as specified under this part of ISO 16017. Each sorbent or product that is identified by a trademarked name is unique and has a sole manufacturer; however, they are widely available from many different suppliers. This information is given for the convenience of users of this part of ISO 16017 and does not constitute an endorsement by ISO of the product named. Equivalent products may be used if they can be shown to lead to the same results.
Abstract
Overview
ISO 16017-1:2000 establishes standardized procedures for the sampling and analysis of volatile organic compounds (VOCs) in air, specifically focusing on pumped sampling using sorbent tube, thermal desorption, and capillary gas chromatography. This international standard is applicable to a wide range of environments including indoor, ambient, and workplace atmospheres, as well as emissions testing from materials in various scales of test chambers. By providing guidance on equipment selection, calibration, and quality control, ISO 16017-1 provides a reliable framework for quantifying VOC levels and supporting air quality assessments.
Key Topics
- Sampling Technique: Use of low flowrate personal sampling pumps in combination with appropriately selected sorbent tubes for the effective collection of airborne VOCs.
- Applicability: Suitable for a broad spectrum of VOCs, including but not limited to hydrocarbons, halogenated hydrocarbons, esters, glycol ethers, ketones, and alcohols.
- Sorbent Selection: Recommends different sorbents based on compound type, volatility, and other properties. Guidance is provided for selecting the optimal sorbent material, with practical advice on their range of applicability.
- Concentration Range: Enables quantitative measurement of airborne VOCs over a range from approximately 0.5 µg/m³ up to 100 mg/m³ per compound, contingent upon the capacity and characteristics of the chosen sorbent.
- Breakthrough and Recovery: Discusses issues such as breakthrough volumes, artifact formation, and partial recovery for certain compounds, and provides strategies to mitigate these effects (e.g., use of back-up sorbent tubes).
- Lab Procedures: Covers requirements for pump calibration, sample tube conditioning, analytical calibration, desorption procedures, and quality control measures.
Applications
ISO 16017-1:2000 is highly valuable in a range of practical scenarios, where accurate VOC analysis is critical:
- Workplace Air Monitoring: Ensures compliance with occupational exposure limits by measuring personal exposure and ambient concentrations of VOCs in industrial or office environments.
- Indoor and Ambient Air Quality: Facilitates studies and regulatory compliance related to the presence of VOCs commonly found in building materials, consumer products, or external pollutants.
- Emission Testing: Supports assessment of VOC emissions from construction materials, furnishings, or chemical products in both small and full-scale environmental chambers.
- Environmental and Health Research: Provides a standardized approach for research institutions and laboratories conducting investigations into air quality impacts and source identification of VOCs.
- Regulatory and Compliance Testing: Used by accredited laboratories and compliance bodies to meet national and international legal requirements for air sampling and reporting.
Related Standards
Several other international standards complement or reference the procedures and principles of ISO 16017-1, ensuring interoperability and broad application across the field of air quality analysis:
- ISO 16017-2: Focuses on diffusive sampling of VOCs using similar analytical principles.
- ISO 5725-1 / ISO 5725-2: Outline principles for accuracy, trueness, and precision in measurement methods, relevant to quality assurance in VOC analysis.
- ISO 6141 / ISO 6145 Series / ISO 6349: Provide standardized methods for preparation and certification of calibration gases crucial for instrument calibration and method validation.
- EN 1076: Defines requirements and test methods for pumped sorbent tubes used in workplace atmosphere monitoring.
By adhering to the procedures set out in ISO 16017-1:2000, stakeholders can achieve reliable, reproducible, and internationally recognized results in VOC sampling and analysis, promoting safety, health, and environmental protection across varying applications.
Технические детали
- Технический комитет
- ISO/TC 146/SC 6 - Indoor air
- SKU
- ISO 16017-1:2000
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