ASTM D7215-22
Standard Test Method for Calculated Flash Point from Simulated Distillation Analysis of Distillate Fuels
Standard Test Method for Calculated Flash Point from Simulated Distillation Analysis of Distillate Fuels
- Статус документа:
- Действующий
- Формат:
- Электронный (PDF)
- Количество страниц:
- 4
- Дата публикации:
- 1 ноября 2022 г.
- Издание:
- D7215
- ICS:
- 75.160.20
SIGNIFICANCE AND USE 4.1 The flash point temperature is one measure of the tendency of the test specimen to form a flammable mixture with air under controlled laboratory conditions. It is only one of a number of properties that must be considered in assessing the overall flammability hazard of a material. 4.2 Flash point is used in shipping and safety regulations to define flammable and combustible materials. Consult the particular regulation involved for precise definitions of these classifications. 4.3 Flash point can indicate the possible presence of highly volatile and flammable materials in a relatively non-volatile or non-flammable material. 4.4 In cases where Test Method D2887 data are available, that is, for determination of boiling range distribution or calculation of other physical properties, this test method provides a calculation method for flash point without performing an additional analysis. Table 1 shows the ranges for the IBP, 5 %, and 10 % results for each equation. 4.5 In the case where the flash point of a fuel has been initially established, the calculated flash point is useful as a flash point check on subsequent samples of that fuel, provided its source and mode of manufacture remain unchanged. SCOPE 1.1 This test method covers the calculated flash point formula, which represents a means for directly estimating the flash point temperature of distillate fuels from Test Method D2887 data. The value computed from the equation is termed the “calculated flash point.” The calculated flash point formula is applicable to diesel fuel samples based on a correlation to Test Method D93 over the range from 47 °C to 99 °C, and to jet fuel samples based on a correlation to Test Method D56 and Test Method D3828 over the range from 35 °C to 67 °C. 1.2 The calculated flash point formula is valid for diesel and jet fuels with an IBP between 90 °C and 162 °C (194 °F and 324 °F), Test Method D2887 5 % recovery temperature between 136 °C and 207 °C (277 °F and 405 °F), and Test Method D2887 10 % recovery temperature between 142 °C and 222 °C (288 °F and 432 °F). For each flash point test method (Test Method D56, Test Method D93, and Test Method D3828) a separate equation has been established. See 4.4 for a detailed overview of the simulated distillation IBP, 5 %, and 10 % ranges per equation. 1.3 A calculated diagnostic parameter, not exceeding a given threshold value, is a prerequisite for acceptance of the calculated flash point. 1.4 The diagnostic parameter MSPEX (Mean Summed Prediction Error) checks the sample compliance, based on reconstruction of TIBP, T5 %, and T10 % of the sample, via a calculation procedure. A value for MSPEX not exceeding the threshold level of 1.9 °C is a prerequisite for accepting the calculated flash point, CFP. Note 1: It is important to note that calculated flash point results, at this time, are not recognized by regulatory organizations in verifying conformance to applicable regulations. Note 2: The calculated flash point derived from simulated distillation data depends upon the accuracy of determination of the IBP temperature and the 5 % and 10 % recovery temperatures. Note 3: If the user's specification requires a defined flash point test method other than this test method, neither this test method nor any other test method should be substituted for the prescribed test method without obtaining comparative data and an agreement from the specifier. 1.5 The values stated in SI units are to be regarded as the standard. 1.5.1 Exception—The values given in parentheses are for information only. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.7 This international standard was developed in acc...
Abstract
Overview
ASTM D7215-22 is the Standard Test Method for Calculated Flash Point from Simulated Distillation Analysis of Distillate Fuels, developed by ASTM International. This standard provides a method to estimate the flash point temperature of distillate fuels, including diesel and jet fuels, using data from simulated distillation performed according to ASTM D2887. The value derived is termed the "calculated flash point" and offers a rapid, data-driven way to assess flammability characteristics without performing a separate flash point test.
Flash point temperature is a crucial property for evaluating the potential flammability hazard of fuels. It plays an important role in shipping, storage, handling, and compliance with safety regulations, and helps in detecting the presence of volatile and combustible material in fuel samples.
Key Topics
-
Calculated Flash Point (CFP):
- Provides direct estimation of flash point temperature based on boiling range distribution data from simulated distillation.
- Applies to diesel fuels (via correlation to ASTM D93) and jet fuels (via correlation to ASTM D56 and D3828).
- Calculation uses initial boiling point (IBP), 5% recovery, and 10% recovery temperatures from ASTM D2887 analysis.
-
Validity and Limitations:
- Valid for diesel and jet fuels with IBP ranging from 90°C to 162°C, 5% recovery from 136°C to 207°C, and 10% recovery from 142°C to 222°C.
- Includes a diagnostic compliance parameter (MSPE) that ensures calculated values are only reported when sample conformity is established.
- Calculated flash point is not a regulatory compliance method and should not replace prescribed flash point test methods unless approved by the specifier.
-
Flash Point Significance:
- Determines the temperature at which fuel vapors may ignite in controlled conditions.
- Used to classify fuels as flammable or combustible under transportation and safety regulations.
- Indicates the presence of highly volatile or dangerous contaminants.
Applications
-
Quality Control: The method enables quick confirmation of flash point for batches where source and manufacturing remain consistent, enhancing efficiency in production laboratories.
-
Process Optimization: Refineries and testing facilities can leverage simulated distillation data to monitor changes in fuel composition and potential volatility issues, supporting operational safety.
-
Screening and Research: Useful for rapidly assessing changes across multiple fuel samples, especially in research and development settings, without the need for repeat physical flash point tests.
-
Compliance Support: Although not a stand-alone method for regulatory verification, the calculated flash point can serve as a preliminary check before conducting official test procedures.
Related Standards
- ASTM D2887 - Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography: Essential for obtaining boiling range data used in flash point calculations.
- ASTM D93 - Test Method for Flash Point by Pensky-Martens Closed Cup Tester: Used as the correlation reference for diesel fuels.
- ASTM D56 - Test Method for Flash Point by Tag Closed Cup Tester: Used as the correlation reference for jet fuels.
- ASTM D3828 - Test Methods for Flash Point by Small Scale Closed Cup Tester: Additional correlation for jet fuels.
- ASTM D975 - Specification for Diesel Fuel Oils.
- ASTM D1655 - Specification for Aviation Turbine Fuels.
- ASTM D4175 - Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants.
- ASTM D6708 - Practice for Statistical Assessment and Improvement of Agreement Between Test Methods.
Practical Value
ASTM D7215-22 delivers significant value for petroleum laboratories, refineries, and fuel quality professionals by enabling a rapid and data-driven estimation of flash point-improving operational control, safety screening, and product consistency. This standard leverages established simulated distillation results, reducing the need for time-consuming and resource-intensive flash point testing, as long as the necessary correlation and compliance criteria are satisfied. For organizations seeking to integrate predictive testing into their quality systems, ASTM D7215-22 offers a practical, efficient approach aligned with international best practices for distillate fuel evaluation.
Технические детали
- Технический комитет
- D02 - Petroleum Products, Liquid Fuels, and Lubricants
- SKU
- ASTM D7215-22
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