SIST EN ISO 16190:2022

Footwear - Critical substances potentially present in footwear and footwear components - Test method to quantitatively determine polycyclic aromatic hydrocarbons (PAHs) in footwear materials (ISO 16190:2021)

Название (английский):

Статус документа:: Действующий
Формат:: Электронный (PDF)
Количество страниц:: 20
Дата публикации:: 9 декабря 2021 г.
Издание:: ISO 16190:2021
ICS:: 61.060

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Описание (английский):

This document specifies a method to determine the amounts of polycyclic aromatic hydrocarbons (PAHs) in footwear and footwear components. NOTE A list of relevant materials can be found in ISO/TR 16178:2021, Table 1[3].

Abstract

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Overview

EN ISO 16190:2021 - Footwear - Test method to quantitatively determine polycyclic aromatic hydrocarbons (PAHs) in footwear materials - is an ISO standard adopted by CEN (EN ISO 16190:2021). It specifies a laboratory method to extract and quantify PAHs in footwear and footwear components, supporting regulatory compliance (e.g., REACH / Regulation (EC) No 1907/2006 and Commission Regulation (EU) 2018/1513) and brand Restricted Substance Lists (RSLs). The method replaces the earlier ISO/TS 16190:2013 and provides a harmonized approach for testing a defined list of PAHs relevant to footwear safety.

Key topics and requirements

Scope and purpose: Quantitative determination of PAHs in a variety of footwear materials (see ISO/TR 16178:2021 for relevant materials).

Target analytes: A list of 24 PAHs (including Benzo[a]pyrene, Benzo[e]pyrene, Chrysene, Benzo[b]fluoranthene, Dibenzo[a,h]anthracene, etc.) that may be relevant for compliance and risk assessment.

Sample preparation and extraction:

Extraction with toluene at 60 °C in an ultrasonic bath for 1 hour (principle described in the standard).
Instructions for sample aliquoting and optional clean-up.

Clean-up: Optional Solid-Phase Extraction (SPE) procedures to reduce matrix interference before instrumental analysis.

Instrumental determination: Analysis by GC‑MS or GC‑MS/MS with guidance on chromatographic conditions and calibration.

Calibration and standards: Preparation of PAH stock and working solutions, with procedures for selecting which PAHs to determine.

Expression of results: Reporting individual PAH concentrations and optional summed PAH values; requirements for test report content and method performance metrics.

Safety: Warnings on handling flammable solvents (toluene) and carcinogenic PAHs, and occupational safety obligations.

Applications and users

This standard is used by:

Laboratories performing conformity and quality testing of footwear materials.

Footwear manufacturers and suppliers implementing product safety and internal RSL compliance.

Brand compliance teams verifying supplier declarations and product releases.

Regulators and market surveillance bodies enforcing chemical limits in consumer products.

Use cases include regulatory compliance (REACH), product development risk assessments, incoming material control, and supplier audits.

Related standards

ISO/TR 16178:2021 - referenced for lists of relevant footwear materials.

Supersedes ISO/TS 16190:2013 (technical specification).

ISO 4787 (laboratory glassware) cited as normative reference.

Keywords: EN ISO 16190:2021, PAHs, footwear testing, polycyclic aromatic hydrocarbons, GC‑MS, toluene extraction, REACH compliance, restricted substances.

SIST EN ISO 16190:2022

Abstract

Похожие стандарты

Overview

Key topics and requirements

Applications and users

Related standards

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