ISO 9924-3:2024 PDF
Rubber and rubber products — Determination of the composition of vulcanizates and uncured compounds by thermogravimetry — Part 3: Hydrocarbon rubbers, halogenated rubbers and polysiloxane rubbers
Rubber and rubber products — Determination of the composition of vulcanizates and uncured compounds by thermogravimetry — Part 3: Hydrocarbon rubbers, halogenated rubbers and polysiloxane rubbers
- Статус документа:
- Действующий
- Формат:
- Электронный (PDF)
- Количество страниц:
- 18
- Дата публикации:
- 29 февраля 2024 г.
- Издание:
- ISO IS 9924 edition 2 version 1
- ICS:
- 83.060
This document specifies a thermogravimetric method for the determination of the main constituents of rubber compounds such as elastomer(s), carbon black and mineral filler. It establishes the “fingerprint” of the tested material. However, the result does not always correspond exactly to the theoretical formula of the rubber. This method applies to raw or compounded rubbers, vulcanized and unvulcanised, with or without extraction. This method applies to rubbers with hydrocarbon backbones (NR, BR, SBR, IIR, EPDM, ACM, AEM, etc.) used alone or as mixtures. For the mixtures, the polymer content corresponds to the total rubber and it is not usually possible to identify individual polymers. This method applies to rubbers with halogenated hydrocarbon backbones (CR, CSM, FKM, CM, CO, ECO, etc.) or containing nitrogen (NBR, HNBR, NBR/PVC, etc.), as well as to their mixtures. However, these rubbers often form carbonaceous residues which interfere with the analysis. Application of an appropriate procedure minimizes these interferences. This method also applies to rubbers with a polysiloxane backbone (VMQ, etc.) and to rubbers not listed above.
Abstract
Overview - ISO 9924-3:2024 (Thermogravimetry for rubber composition)
ISO 9924-3:2024 specifies a thermogravimetric analysis (TGA) method to determine the main constituents of rubber compounds - notably elastomer(s), carbon black and mineral fillers - for vulcanizates and uncured compounds. The method produces a characteristic thermogram or “fingerprint” of the tested material. It applies to a wide range of rubbers including hydrocarbon rubbers (NR, BR, SBR, EPDM, etc.), halogenated and nitrogen-containing rubbers (CR, FKM, NBR, HNBR, etc.), and polysiloxane rubbers (VMQ). The standard covers raw and compounded materials, vulcanized and unvulcanized, with or without prior extraction.
Key technical topics and requirements
- Principle: Controlled heating of a weighed test portion under an inert atmosphere (nitrogen) followed by oxidation (air or oxygen) to record mass loss vs temperature/time (TGA curve) and its derivative (dw/dT).
- Reagents & gases: High-purity nitrogen (≥ 99.995% mass fraction, O2
Технические детали
- Технический комитет
- ISO/TC 45/SC 2 - Testing and analysis
- SKU
- ISO 9924-3:2024
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